Applied thermodynamics of fluids / edited by A.R.H. Goodwin, J.V. Sengers, C.J. Peters.

• Author: Royal Society of Chemistry (Great Britain)
• TeilnehmendeR: Goodwin, A. R. H.; Sengers, J. V.; Peters, Cor J.; Royal Society of Chemistry (Great Britain); International Union of Pure and Applied Chemistry. Physical and Biophysical Chemistry Division.; International Association of Chemical Thermodynamics.; ProQuest (Firm)
• Year of Publication: 2010
• Language: English
• Physical Description: xxiii, 509 p. :; ill.
• Other title: Introduction /; References --; Fundamental Considerations /; Introduction --; Basic Thermodynamics --; Homogeneous Functions --; Thermodynamic Properties from Differentiation of Fundamental Equations --; Deviation Functions --; Residual Functions --; Evaluation of Residual Functions --; Mixing and Departure Functions --; Departure Functions with Temperature, Molar Volume and Composition as the Independent Variables --; Departure Functions with Temperature, Pressure and Composition as the Independent Variables --; Mixing and Excess Functions --; Partial Molar Properties --; Fugacity and Fugacity Coefficients --; Activity Coefficients --; The Phase Rule --; Equilibrium Conditions --; Phase Equilibria --; Chemical Equilibria --; Stability and the Critical State --; Densities and Fields --; Stability.; Critical State --; The Virial Equation of State /; Temperature Dependence of the Virial Coefficients --; Composition Dependence of the Virial Coefficients --; Convergence of the Virial Series --; The Pressure Series --; Theoretical Background --; Virial Coefficients of Hard-Core-Square-Well Molecules --; Thermodynamic Properties of Gases --; Perfect-gas and Residual Properties --; Helmholtz Energy and Gibbs Energy --; Perfect-Gas Properties --; Residual Properties --; Estimation of Second and Third Virial Coefficients --; Application of Intermolecular Potential-energy Functions --; Corresponding-states Methods --; Cubic and Generalized van der Waals Equations of State /; Cubic Equation of State Formulation --; The van der Waals Equation of State (1873) --; The Redlich and Kwong Equation of State (1949).; The Soave, Redlich and Kwong Equation of State (1972) --; The Peng and Robinson Equation of State (1976) --; The Patel and Teja (PT) Equation of State (1982) --; The α Parameter --; Volume Translation --; The Elliott, Suresh and Donohue (ESD) Equation of State (1990) --; Higher-Order Equations of State Rooted to the Cubic Equations of State --; Extension of Cubic Equations of State to Mixtures --; Applications --; Pure Components --; Oil and Gas Industry -- Hydrocarbons and Petroleum Fractions --; Chemical Industry -- Polar and Hydrogen Bonding Fluids --; Polymers --; Transport Properties --; Conclusions --; Mixing and Combining Rules /; The Virial Equation of State --; Cubic Equations of State --; Mixing Rules --; Combining Rules --; Non-Quadratic Mixing and Combining Rules --; Mixing Rules that Combine an Equation of State with an Activity-Coefficient Model.; Multi-Parameter Equations of State --; Benedict, Webb, and Rubin Equation of State --; Generalization with the Acentric Factor --; Helmholtz-Function Equations of State --; Mixing Rules for Hard Spheres and Association --; Mixing and Combining Rules for SAFT --; Cubic Plus Association Equation of State --; The Corresponding-States Principle /; Theoretical Considerations --; Determination of Shape Factors --; Other Reference Fluids --; Exact Shape Factors --; Shape Factors from Generalized Equations of State --; Mixtures --; van der Waals One-Fluid Theory --; Mixture Corresponding-States Relations --; Applications of Corresponding-States Theory --; Extended Corresponding-States for Natural Gas Systems --; Extended Lee-Kesler --; Generalized Crossover Cubic Equation of State --; Thermodynamics of Fluids at Meso and Nano Scales /; Thermodynamic Approach to Meso-Heterogeneous Systems --; Equilibrium Fluctuations --; Local Helmholtz Energy --; Applications of Meso-Thermodynamics --; Van der Waals Theory of a Smooth Interface --; Polymer Chain in a Dilute Solution --; Building a Nanoparticle Through Self Assembly --; Modulated Fluid Phases --; Meso-Thermodynamics of Criticality --; Critical Fluctuations --; Scaling Relations --; Near-Critical Interface --; Divergence of Tolman's Length --; Competition of Meso-Scales --; Crossover to Tricriticality in Polymer Solutions --; Tolman's Length in Polymer Solutions --; Finite-size Scaling --; Non-Equilibrium Meso-Thermodynamics of Fluid Phase Separation --; Relaxation of Fluctuations --; Critical Slowing Down --; Homogeneous Nucleation --; Spinodal Decomposition --; Conclusion --; SAFT Associating Fluids and Fluid Mixtures /; Statistical Mechanical Theories of Association and Wertheim's Theory --; SAFT Equations of State --; SAFT-HS and SAFT-HR --; Soft-SAFT --; SAFT-VR --; PC-SAFT --; Summary --; Extensions of the SAFT Approach --; Modelling the Critical Region --; Polar Fluids --; Ion-Containing Fluids --; Modelling Inhomogeneous Fluids --; Dense Phases: Liquid Crystals and Solids --; Parameter Estimation: Towards more Predictive Approaches --; Pure-component Parameter Estimation --; Use of Quantum Mechanics in SAFT Equations of State --; Unlike Binary Intermolecular Parameters --; SAFT Group-Contribution Approaches --; Homonuclear Group-Contribution Models in SAFT --; Heteronuclear Group Contribution Models in SAFT --; Concluding Remarks --; Polydisperse Fluids /; Influence of Polydispersity on the Liquid + Liquid Equilibrium of a Polymer Solution.; Approaches to Polydispersity --; The Pseudo-component Method --; Continuous Thermodynamics --; Application to Real Systems --; Polymer Systems --; Petroleum Fluids, Asphaltenes, Waxes and Other Applications --; Thermodynamic Behaviour of Fluids near Critical Points /; General Theory of Critical Behaviour --; Scaling Fields, Critical Exponents, and Critical Amplitudes --; Parametric Equation of State --; One-Component Fluids --; Simple Scaling --; Revised Scaling --; Complete Scaling --; Vapour-Liquid Equilibrium --; Symmetric Corrections to Scaling --; Binary Fluid Mixtures --; Isomorphic Critical Behaviour of Mixtures --; Incompressible Liquid Mixtures --; Weakly Compressible Liquid Mixtures --; Compressible Fluid Mixtures --; Dilute Solutions --; Crossover Critical Behaviour --; Crossover from Ising-like to Mean-Field Critical Behaviour.; Effective Critical Exponents --; Global Crossover Behaviour of Fluids --; Discussion --; Acknowledgements --; Phase Behaviour of Ionic Liquid Systems /; Phase Behaviour of Binary Ionic Liquid Systems --; Phase Behaviour of (Ionic Liquid + Gas Mixtures) --; Phase Behaviour of (Ionic Liquid + Water) --; Phase Behaviour of (Ionic Liquid + Organic) --; Phase Behaviour of Ternary Ionic Liquid Systems --; Phase Behaviour of (Ionic Liquid + Carbon Dioxide + Organic) --; Phase Behaviour of (Ionic Liquid + Aliphatic + Aromatic) --; Phase Behaviour of (Ionic Liquid + Water + Alcohol) --; Phase Behaviour of Ionic Liquid Systems with Azeotropic Organic Mixtures --; Modeling of the Phase Behaviour of Ionic Liquid Systems --; Molecular Simulations --; Excess Gibbs-energy Methods --; Equation of State Modeling --; Quantum Chemical Methods --; Multi-parameter Equations of State for Pure Fluids and Mixtures /; The Development of a Thermodynamic Property Formulation --; Fitting an Equation of State to Experimental Data --; Recent Nonlinear Fitting Methods --; Pressure-Explicit Equations of State --; Cubic Equations --; The Benedict-Webb-Rubin Equation of State --; The Bender Equation of State --; The Jacobsen-Stewart Equation of State --; Thermodynamic Properties from Pressure-Explicit Equations of State --; Fundamental Equations --; The Equation of Keenan, Keyes, Hill, and Moore --; The Equations of Haar, Gallagher, and Kell --; The Equation of Schmidt and Wagner --; Reference Equations of Wagner --; Technical Equations of Span and of Lemmon --; Recent Equations of State.; Applied Non-Equilibrium Thermodynamics /; A Systematic Thermodynamic Theory for Transport --; On the Validity of the Assumption of Local Equilibrium --; Concluding remarks --; Fluxes and Forces from the Second Law of Thermodynamics --; Continuous phases --; Maxwell-Stefan Equations --; Discontinuous Systems --; Chemical Reactions --; Thermal Diffusion in a Reacting System --; Mesoscopic Description Along the Reaction Coordinate --; Heterogeneous Catalysis --; The Path of Energy-Efficient Operation --; An Optimisation Procedure --; Optimal Heat Exchange --; The Highway Hypothesis for a Chemical Reactor --; Energy-Efficient Production of Hydrogen Gas --; References.
• Bibliography: Includes bibliographical references and index.
• ISBN: 9781847558060 (hbk.); 1847558062 (hbk.); 9781849730983 (electronic bk.)
• Hierarchical level: Monograph
• Statement of Responsibility: edited by A.R.H. Goodwin, J.V. Sengers, C.J. Peters.