Carbanion Chemistry / / Robert B. Bates, Craig A. Ogle.

• Superior document: Title is part of eBook package: De Gruyter DGBA Physical Sciences <1990
• VerfasserIn: Bates, Robert B.,; Ogle, Craig A.,
• Place / Publishing House: Berlin ;, Boston : : De Gruyter, , [2022]; ©1983
• Year of Publication: 2022
• Edition: Reprint 2021
• Language: English
• Physical Description: 1 online resource (104 p.)

Table of Contents

• Frontmatter
• Preface
• Table of Contents
• I. Introduction
• II. Structures
• 1. Non-delocalized (σ)
• 2. Delocalized (π)
• III. Preparations
• 1. From Alkyl Halides
• 2. From Alkanes by Proton Abstraction (3-2)
• 3. From Unsaturated Compounds
• 4. From Other Organometallics by Changing the Metal
• IV. Reactions of a Carbanions with Electrophiles
• 1. Substitution Reactions of Alkyl (sp3) Anions
• 2. Addition Reactions of Alkyl (sp3) Anions
• 3. Vinyl (sp2), Aryl (sp2), and Acetylenic (sp) Anions
• V. Reactions of π Carbanions with Electrophiles π
• 1. Hydrocarbon π Anions
• 2. Enolate Anions
• 3. Other O-Stabilized Monoanions
• 4. O-Stabilized Dianions
• 5. N-Stabilized Anions
• 6. S-Stabilized Anions
• VI. Eliminations
• 1. α-Eliminations
• 2. β-Eliminations
• 3. γ-Eliminations
• 4. δ-Eliminations
• 5. Cycloeliminations
• VII. Oxidations
• 1. Oxidations to Hydroperoxides, Alcohols, and Ketones
• 2. Oxidative Couplings
• 3. Dianion Oxidations
• Vm. Rearrangements
• 1. Intermolecular Rearrangements
• 2. Intramolecular Additions
• 3. Intramolecular Eliminations
• 4. Sigmatropic Carbanion Rearrangements
• 4. Sigmatropic Carbanion Rearrangements
• 6. Complex Intramolecular Rearrangements
• IX. Carbanion Equivalents
• X. Summary
• XI. References