Carbanion Chemistry / / Robert B. Bates, Craig A. Ogle.

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Bibliographic Details
Superior document:Title is part of eBook package: De Gruyter DGBA Physical Sciences <1990
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Place / Publishing House:Berlin ;, Boston : : De Gruyter, , [2022]
©1983
Year of Publication:2022
Edition:Reprint 2021
Language:English
Online Access:
Physical Description:1 online resource (104 p.)
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Description
Other title:Frontmatter --
Preface --
Table of Contents --
I. Introduction --
II. Structures --
1. Non-delocalized (σ) --
2. Delocalized (π) --
III. Preparations --
1. From Alkyl Halides --
2. From Alkanes by Proton Abstraction (3-2) --
3. From Unsaturated Compounds --
4. From Other Organometallics by Changing the Metal --
IV. Reactions of a Carbanions with Electrophiles --
1. Substitution Reactions of Alkyl (sp3) Anions --
2. Addition Reactions of Alkyl (sp3) Anions --
3. Vinyl (sp2), Aryl (sp2), and Acetylenic (sp) Anions --
V. Reactions of π Carbanions with Electrophiles π --
1. Hydrocarbon π Anions --
2. Enolate Anions --
3. Other O-Stabilized Monoanions --
4. O-Stabilized Dianions --
5. N-Stabilized Anions --
6. S-Stabilized Anions --
VI. Eliminations --
1. α-Eliminations --
2. β-Eliminations --
3. γ-Eliminations --
4. δ-Eliminations --
5. Cycloeliminations --
VII. Oxidations --
1. Oxidations to Hydroperoxides, Alcohols, and Ketones --
2. Oxidative Couplings --
3. Dianion Oxidations --
Vm. Rearrangements --
1. Intermolecular Rearrangements --
2. Intramolecular Additions --
3. Intramolecular Eliminations --
4. Sigmatropic Carbanion Rearrangements --
6. Complex Intramolecular Rearrangements --
IX. Carbanion Equivalents --
X. Summary --
XI. References
Format:Mode of access: Internet via World Wide Web.
ISBN:9783112544242
9783110637243
DOI:10.1515/9783112544242
Access:restricted access
Hierarchical level:Monograph
Statement of Responsibility: Robert B. Bates, Craig A. Ogle.