Organophosphorus Chemistry 2018 / / György Keglevich.
Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses....
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Place / Publishing House: | [Place of publication not identified] : : MDPI - Multidisciplinary Digital Publishing Institute,, 2020. |
Year of Publication: | 2020 |
Language: | English |
Physical Description: | 1 online resource (601 pages) |
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Keglevich, György, author. Organophosphorus Chemistry 2018 / György Keglevich. [Place of publication not identified] : MDPI - Multidisciplinary Digital Publishing Institute, 2020. 1 online resource (601 pages) text txt rdacontent computer c rdamedia online resource cr rdacarrier Description based on online resource; title from PDF title page (MDPI - Multidisciplinary Digital Publishing Institute, viewed June 27, 2023). Organophosphorus chemistry is an important discipline within organic chemistry. Phosphorus compounds, such as phosphines, trialkyl phosphites, phosphine oxides (chalcogenides), phosphonates, phosphinates and >P(O)H species, etc., may be important starting materials or intermediates in syntheses. Let us mention the Wittig reaction and the related transformations, the Arbuzov- and the Pudovik reactions, the Kabachnik-Fields condensation, the Hirao reaction, the Mitsunobu reaction, etc. Other reactions, e.g., homogeneous catalytic transformations or C-C coupling reactions involve P-ligands in transition metal (Pt, Pd, etc.) complex catalysts. The synthesis of chiral organophosphorus compounds means a continuous challenge.Methods have been elaborated for the resolution of tertiary phosphine oxides and for stereoselective organophosphorus transformations. P-heterocyclic compounds, including aromatic and bridged derivatives, P-functionalized macrocycles, dendrimers and low coordinated P-fragments, are also of interest. An important segment of organophosphorus chemistry is the pool of biologically-active compounds that are searched and used as drugs, or as plant-protecting agents. The natural analogue of P-compounds may also be mentioned. Many new phosphine oxides, phosphinates, phosphonates and phosphoric esters have been described, which may find application on a broad scale. Phase transfer catalysis, ionic liquids and detergents also have connections to phosphorus chemistry. Green chemical aspects of organophosphorus chemistry (e.g., microwave-assisted syntheses,solvent-free accomplishments, optimizations, and atom-efficient syntheses) represent a dynamically developing field. Last, but not least, theoretical approaches and computational chemistry are also a strong sub-discipline within organophosphorus chemistry. Chemistry, Organic. 3-03928-237-9 |
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Keglevich, György, |
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Keglevich, György, Organophosphorus Chemistry 2018 / |
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Keglevich, György, |
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Keglevich, György, |
title |
Organophosphorus Chemistry 2018 / |
title_full |
Organophosphorus Chemistry 2018 / György Keglevich. |
title_fullStr |
Organophosphorus Chemistry 2018 / György Keglevich. |
title_full_unstemmed |
Organophosphorus Chemistry 2018 / György Keglevich. |
title_auth |
Organophosphorus Chemistry 2018 / |
title_new |
Organophosphorus Chemistry 2018 / |
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organophosphorus chemistry 2018 / |
publisher |
MDPI - Multidisciplinary Digital Publishing Institute, |
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2020 |
physical |
1 online resource (601 pages) |
isbn |
3-03928-237-9 |
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Q - Science |
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QD - Chemistry |
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QD251 |
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500 - Science |
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540 - Chemistry |
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547 - Organic chemistry |
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547 |
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