Solid-phase microextraction and related techniques in bioanalysis / / Hiroyuki Kataoka, editor.

• TeilnehmendeR: Kataoka, Hiroyuki,
• Place / Publishing House: Basel : : MDPI,, [2023]; ©2023
• Year of Publication: 2023
• Language: English
• Physical Description: 1 online resource

Bioanalysis of endogenous substances, metabolites, and contaminants poisons is important in analyses of biological functions, metabolomics, forensic toxicology, patient diagnosis and biomonitoring of human exposure to hazardous chemicals. In these analyses, methods of sample preparation are essential for the isolation and concentration of target analytes from complex biological matrices. These processes, however, are time-consuming, labor-intensive and error-prone, and markedly influence the reliability and accuracy of determining target analytes. Thus, efficient sample preparation techniques and their integration with analytical methods have become significant. Solid-phase microextraction (SPME) is a simple and convenient sample preparation technique that has enabled automation, miniaturization, high-throughput performance, and online coupling with analytical instruments. Moreover, SPME has reduced analysis times, as well as solvent and disposal costs. This book consists of 14 original, peer-reviewed papers for the Special Issue in the MDPI journal Molecules. The topics covered include headspace fiber SPME (HS-SPME) gas chromatography-mass spectrometry (GC-MS), HS-in-needle microextraction GC-MS, thin film SPME liquid chromatography-tandem mass spectrometry (LC-MS/MS), magnetic solid phase extraction LC-MS/MS, in-tube SPME LC-MS/MS and in-tube SPME LC-UV. Samples analyzed include plant-derived volatile organic compounds; body odor; metabolites in urine, plasma and saliva sample; and biomarkers of tobacco smoke exposure in hair and environmental estrogens.

Table of Contents

About the Editor vii -- Preface to "Solid-Phase Microextraction and Related Techniques in Bioanalysis" ix -- Hiroyuki Kataoka -- Solid-Phase Microextraction and Related Techniques in Bioanalysis -- Reprinted from: Molecules 2023, 28, 2467, doi:10.3390/molecules28062467 1 -- Yesenia Mendoza Garc´ıa, Ana Luiza Coeli Cruz Ramos, Ana Cardoso Clemente Filha Ferreira -- de Paula, Maicon Heitor do Nascimento, Rodinei Augusti and Raquel Linhares Bello de -- Ara ´ujo et al. -- Chemical Physical Characterization and Profile of Fruit Volatile Compounds from Different -- Accesses of Myrciaria floribunda (H. West Ex Wild.) O. Berg through Polyacrylate Fiber -- Reprinted from: Molecules 2021, 26, 5281, doi:10.3390/molecules26175281 5 -- Ana P. X. Mariano, Ana L. C. C. Ramos, Afonso H. de Oliveira J ´unior, Yesenia M. Garc´ıa, Ana -- C. C. F. F. de Paula and Mauro R. Silva et al. -- Optimization of Extraction Conditions and Characterization of Volatile Organic Compounds of -- Eugenia klotzschiana O. Berg Fruit Pulp -- Reprinted from: Molecules 2022, 27, 935, doi:10.3390/molecules27030935 19 -- Yuri G. Figueiredo, Eduardo A. Corr ˆea, Afonso H. de Oliveira Junior, Ana C. d. C. Mazzinghy, -- Henrique d. O. P. Mendon¸ca and Yan J. G. Lobo et al. -- Profile of Myracrodruon urundeuva Volatile Compounds Ease of Extraction and Biodegradability -- and In Silico Evaluation of Their Interactions with COX-1 and iNOS -- Reprinted from: Molecules 2022, 27, 1633, doi:10.3390/molecules27051633 33 -- Zhenying Liu, Ye Fang, Cui Wu, Xian Hai, Bo Xu and Zhuojun Li et al. -- The Difference of Volatile Compounds in Female and Male Buds of Herpetospermum -- pedunculosum Based on HS-SPME-GC-MS and Multivariate Statistical Analysis -- Reprinted from: Molecules 2022, 27, 1288, doi:10.3390/molecules27041288 53 -- Lijun Cai, Sarina Macfadyen, Baozhen Hua, Haochuan Zhang, Wei Xu and Yonglin Ren -- Identification of Biomarker Volatile Organic Compounds Released by Three Stored-Grain Insect -- Pests in Wheat -- Reprinted from: Molecules 2022, 27, 1963, doi:10.3390/molecules27061963 65 -- Qasim Ahmed, Manjree Agarwal, Ruaa Alobaidi, Haochuan Zhang and Yonglin Ren -- Response of Aphid Parasitoids to Volatile Organic Compounds from Undamaged and Infested -- Brassica oleracea with Myzus persicae -- Reprinted from: Molecules 2022, 27, 1522, doi:10.3390/molecules27051522 75 -- Keita Saito, Yoshiyuki Tokorodani, Chihiro Sakamoto and Hiroyuki Kataoka -- Headspace Solid-Phase Microextraction/Gas Chromatography-Mass Spectrometry for the -- Determination of 2-Nonenal and Its Application to Body Odor Analysis -- Reprinted from: Molecules 2021, 26, 5739, doi:10.3390/molecules26195739 89 -- Sehyun Kim and Sunyoung Bae -- In Vitro and In Vivo Human Body Odor Analysis Method Using GO:PANI/ZNRs/ZIF´8 -- Adsorbent Followed by GC/MS -- Reprinted from: Molecules 2022, 27, 4795, doi:10.3390/molecules27154795 99 -- Kamil Łuczykowski, Natalia Warmuzi ´nska, Sylwia Operacz, Iga Stryjak, Joanna -- Bogusiewicz and Julia Jacyna et al. -- Metabolic Evaluation of Urine from Patients Diagnosed with High Grade (HG) Bladder Cancer -- by SPME-LC-MS Method -- Reprinted from: Molecules 2021, 26, 2194, doi:10.3390/molecules26082194 113 -- Andrea Speltini, Francesca Merlo, Federica Maraschi, Giorgio Marrubini, Anna Faravelli and -- Antonella Profumo -- Magnetic Micro-Solid-Phase Extraction Using a Novel Carbon-Based Composite Coupled with -- HPLC-MS/MS for Steroid Multiclass Determination in Human Plasma -- Reprinted from: Molecules 2021, 26, 2061, doi:10.3390/molecules26072061 125 -- Hiroyuki Kataoka and Daiki Nakayama -- Online In-Tube Solid-Phase Microextraction Coupled with Liquid Chromatography-Tandem -- Mass Spectrometry for Automated Analysis of Four Sulfated Steroid Metabolites in Saliva -- Samples -- Reprinted from: Molecules 2022, 27, 3225, doi:10.3390/molecules27103225 141 -- Hiroyuki Kataoka, Sanae Kaji and Maki Moai -- Risk Assessment of Passive Smoking Based on Analysis of Hair Nicotine and Cotinine as -- Exposure Biomarkers by In-Tube Solid-Phase Microextraction Coupled On-Line to LC-MS/MS -- Reprinted from: Molecules 2021, 26, 7356, doi:10.3390/molecules26237356 153 -- Atsushi Ishizaki and Hiroyuki Kataoka -- Online In-Tube Solid-Phase Microextraction Coupled to Liquid Chromatography-Tandem -- Mass Spectrometry for the Determination of Tobacco-Specific Nitrosamines in Hair Samples -- Reprinted from: Molecules 2021, 26, 2056, doi:10.3390/molecules26072056 163 -- Yuping Zhang, Ning Wang, Zhenyu Lu, Na Chen, Chengxing Cui and Xinxin Chen -- Smart Titanium Wire Used for the Evaluation of Hydrophobic/Hydrophilic Interaction by -- In-Tube Solid Phase Microextraction -- Reprinted from: Molecules 2022, 27, 2353, doi:10.3390/molecules27072353 173.