Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / / Daniel Knoll.
The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One r...
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Superior document: | Beiträge zur organischen Synthese 85 |
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Place / Publishing House: | Berlin, Germany : : Logos Verlag Berlin GmbH,, [2020] ©2020 |
Year of Publication: | 2020 |
Language: | English |
Series: | Beiträge zur organischen Synthese
85 |
Physical Description: | 1 online resource (xiii, 212 pages) :; illustrations; digital file(s). |
Notes: | Author's doctoral thesis, Karlsruher Institut für Technologie (KIT) -- title-page recto. |
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Knoll, Daniel, author. Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / Daniel Knoll. Berlin/Germany Logos Verlag Berlin 2020 Berlin, Germany : Logos Verlag Berlin GmbH, [2020] ©2020 1 online resource (xiii, 212 pages) : illustrations; digital file(s). text txt rdacontent computer c rdamedia online resource cr rdacarrier text file rda Beiträge zur organischen Synthese 85 Author's doctoral thesis, Karlsruher Institut für Technologie (KIT) -- title-page recto. Includes bibliographical references. Also available in print form. In English with abstract in German. Description based on e-publication, viewed on August 6, 2021. The most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes. In this work, [2.2]paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability. To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. CC BY-NC-ND Heterobimetallic complexes. Paracyclophane Catalysis Heterobimetallic Complexes Photocatalysis Cooperative Effects Karlsruher Institut für Technologie, degree awarding institution. Print version: 3832550712 |
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English |
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author |
Knoll, Daniel, |
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Knoll, Daniel, Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / Beiträge zur organischen Synthese |
author_facet |
Knoll, Daniel, Karlsruher Institut für Technologie, Karlsruher Institut für Technologie, |
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VerfasserIn |
author2 |
Karlsruher Institut für Technologie, |
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author_corporate |
Karlsruher Institut für Technologie, |
author_sort |
Knoll, Daniel, |
title |
Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / |
title_full |
Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / Daniel Knoll. |
title_fullStr |
Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / Daniel Knoll. |
title_full_unstemmed |
Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / Daniel Knoll. |
title_auth |
Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / |
title_new |
Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / |
title_sort |
heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / |
series |
Beiträge zur organischen Synthese |
series2 |
Beiträge zur organischen Synthese |
publisher |
Logos Verlag Berlin Logos Verlag Berlin GmbH, |
publishDate |
2020 |
physical |
1 online resource (xiii, 212 pages) : illustrations; digital file(s). Also available in print form. |
isbn |
9783832550714 3832550712 |
illustrated |
Illustrated |
oclc_num |
1202548664 |
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Beiträge zur organischen Synthese 85 |
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Heterobimetallic [2.2]paracyclophane complexes and their application in photoredox catalysis / |
container_title |
Beiträge zur organischen Synthese 85 |
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