Phase-field Modeling of Phase Changes and Mechanical Stresses in Electrode Particles of Secondary Batteries

Most storage materials exhibit phase changes, which cause stresses and, thus, lead to damage of the electrode particles. In this work, a phase-field model for the cathode material NaxFePO4 of Na-ion batteries is studied to understand phase changes and stress evolution. Furthermore, we study the part...

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Superior document:Schriftenreihe des Instituts für Angewandte Materialien, Karlsruher Institut für Technologie
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Year of Publication:2021
Language:English
Series:Schriftenreihe des Instituts für Angewandte Materialien, Karlsruher Institut für Technologie
Physical Description:1 electronic resource (224 p.)
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520 |a Most storage materials exhibit phase changes, which cause stresses and, thus, lead to damage of the electrode particles. In this work, a phase-field model for the cathode material NaxFePO4 of Na-ion batteries is studied to understand phase changes and stress evolution. Furthermore, we study the particle size and SOC dependent miscibility gap of the nanoscale insertion materials. Finally, we introduce the nonlocal species concentration theory, and show how the nonlocality influences the results. 
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653 |a Phasenfeldansatz 
653 |a Phasentrennung 
653 |a Nichtlokalität 
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653 |a Sekundärbatterien 
653 |a Phase-field approach 
653 |a Phase segregation 
653 |a Nonlocality 
653 |a Finite deformation elasticity 
653 |a Secondary batteries 
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