Coordination Chemistry of Silicon
The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone...
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Year of Publication: | 2019 |
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Physical Description: | 1 electronic resource (225 p.) |
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Inoue, Shigeyoshi auth Coordination Chemistry of Silicon MDPI - Multidisciplinary Digital Publishing Institute 2019 1 electronic resource (225 p.) text txt rdacontent computer c rdamedia online resource cr rdacarrier The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist's viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds. English cluster molecular orbital analysis bond activation X-ray diffraction silsesquioxanes digermacyclobutadiene intermetallic bond germanium computational chemistry ?-electron systems isocyanide X-ray crystallography cyclic organopolysilane disilene ruthenium platinum DFT Photostability silicon surfaces stereochemistry palladium distorted coordination <sup>29</sup>Si NMR spectroscopy organosilicon disilanylene polymer Si–Cl activation adsorption AIM siliconoid nanoparticle disiloxane tetrols germylene hydrogen bonding TiO<sub>2</sub> dehydrogenative alkoxylation siloxanes 2-silylpyrrolidines bonding analysis ?-chloro-?-hydrooligosilane hydrido complex oxidative addition photoreaction template surface modification titanium bromosilylenes host-guest chemistry hydrogen bonds salt-free <i>N</i>-heterocyclic carbines silicon cluster condensation silyliumylidenes Baird’s rule <i>N</i>-heterocyclic carbenes reductant main group coordination chemistry molecular cage subvalent compounds isomerization silanetriols germathioacid chloride dehydrobromination <i>N</i>-heterocyclic carbene mechanistic insights ligand-exchange reaction bridging silylene ligand dye-sensitized solar cell silylene computation functionalization silicon digermene <i>N</i>-Heterocyclic tetrylene density functional theory primary silane small molecule activation excited state aromaticity germanethione supramolecular chemistry 3-03897-638-5 |
language |
English |
format |
eBook |
author |
Inoue, Shigeyoshi |
spellingShingle |
Inoue, Shigeyoshi Coordination Chemistry of Silicon |
author_facet |
Inoue, Shigeyoshi |
author_variant |
s i si |
author_sort |
Inoue, Shigeyoshi |
title |
Coordination Chemistry of Silicon |
title_full |
Coordination Chemistry of Silicon |
title_fullStr |
Coordination Chemistry of Silicon |
title_full_unstemmed |
Coordination Chemistry of Silicon |
title_auth |
Coordination Chemistry of Silicon |
title_new |
Coordination Chemistry of Silicon |
title_sort |
coordination chemistry of silicon |
publisher |
MDPI - Multidisciplinary Digital Publishing Institute |
publishDate |
2019 |
physical |
1 electronic resource (225 p.) |
isbn |
3-03897-638-5 |
illustrated |
Not Illustrated |
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AT inoueshigeyoshi coordinationchemistryofsilicon |
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(CKB)4920000000094944 (oapen)https://directory.doabooks.org/handle/20.500.12854/44062 (EXLCZ)994920000000094944 |
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Coordination Chemistry of Silicon |
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1787548505103925249 |
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