Modern Syntheses of Cobalt (III) Complexes / / M. Shibata.

• VerfasserIn: Shibata, M.,
• Place / Publishing House: Berlin ;, Boston : : De Gruyter, , [2022]; ©1983
• Year of Publication: 2022
• Edition: Reprint 2022
• Language: German
• Physical Description: 1 online resource (130 p.) :; With 44 Figures and 31 Tables

Table of Contents

• Frontmatter
• Preface
• Table of Contents
• Abbreviations
• 1 Some Modern Methods of General Syntheses
• 1.1 Significance of Preparative Work
• 1.2 Complexes with Flexible Quadridentate Ligands
• 1.3 Complexes with Macrocyclic Quadridentate Ligand
• 1.4 Complexes Containing α,ω-Alkanediamines
• 1.5 Mixed Cyano Complexes
• 1.6 References
• 2 Versatile Uses of Tricarbonatocobaltate(III) as Starting Material
• 2.1 Historical
• 2.2 Tricarbonatocobaltate(III) Anion
• 2.3 Systematic Synthesis of Complexes
• 2.4 General Syntheses of Tris(bidentate) Complexes
• 2.5 General Syntheses of Amino Acid Complexes
• 2.6 Binuclear Complexes
• 2.7 Heteropoly Electrolytes
• 2.8 Reaction Kinetics Concerning Tricarbonatocobaltate(III)
• 2.9 References
• 3 Preparative Application of Chromatography
• 3.1 Introduction
• 3.2 Chromatography on Ion-Exchange Resins
• 3.3 Chromatography on Ion-Exchange Cellulose or Ion-Exchange Dextran
• 3.4 Chromatography using Cellulose Powder, Paper, or Alumina
• 3.5 References
• 4 Stereoselectivity in Complexes with Less Puckered Chelate Rings
• 4.1 Historical Background
• 4.2 Complexes with Amino Acids
• 4.3 Optically Active Aspartate Containing Complexes
• 4.4 Mixed Diamine-Amino Acid Complexes
• 4.5 Dipeptide Complexes
• 4.6 Tris-Complexes of 3-Substituted Camphor
• 4.7 Complexes Containing Optically Active Tartaric Acid
• 4.8 References
• 5 Design of Low Symmetry Complexes
• 5.1 Introduction
• 5.2 Complexes Exhibiting Marked Splitting in the Second Absorption Bands
• 5.3 Complexes with Optical Activity Due to Unidentate Ligands
• 5.4 Chiral Complexes of the [Co(0)4(N)2]-and [Co(0)2(N)4]+Types
• 5.5 References