The Properties of Energetic Materials : : Sensitivity, Physical and Thermodynamic Properties / / Mohammad Hossein Keshavarz, Thomas M. Klapötke.

• Superior document: Title is part of eBook package: De Gruyter DG Plus eBook-Package 2018
• VerfasserIn: Keshavarz, Mohammad Hossein,; Klapötke, Thomas M.,
• Place / Publishing House: Berlin ;, Boston : : De Gruyter, , [2017]; ©2018
• Year of Publication: 2017
• Language: English
• Series: De Gruyter Textbook
• Physical Description: 1 online resource (XII, 195 p.)

For a chemist who is concerned with the synthesis of new energetic compounds, it is essential to be able to assess physical and thermodynamic properties, as well as the sensitivity, of possible new energetic compounds before synthesis is attempted. Various approaches have been developed to predict important aspects of the physical and thermodynamic properties of energetic materials including (but not limited to): crystal density, heat of formation, melting point, enthalpy of fusion and enthalpy of sublimation of an organic energetic compound. Since an organic energetic material consists of metastable molecules capable of undergoing very rapid and highly exothermic reactions, many methods have been developed to estimate the sensitivity of an energetic compound with respect to detonationcausing external stimuli such as heat, friction, impact, shock and electrostatic discharge. This book introduces these methods and demonstrates those methods which can be easily applied.

Table of Contents

Frontmatter -- Preface -- About the authors -- Contents -- 1. Crystal density -- 2. Heat of formation -- 3. Melting point -- 4. Enthalpy and entropy of fusion -- 5. Heat of sublimation -- 6. Impact sensitivity -- 7. Electric spark sensitivity -- 8. Shock sensitivity -- 9. Friction sensitivity -- 10. Heat sensitivity -- 11. Relationships between different sensitivities -- Problems -- Answers to Problems -- List of symbols -- A. Glossary of compound names and heats of formation for pure as well as composite explosives -- B. Calculation of the gas phase standard enthalpies of formation -- References -- Index