The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / / C. C. Chancey, M. C.M. O'Brien.
Because of the high symmetry involved, the Jahn-Teller effect is the natural starting point for considering electron-phonon (or vibronic) interactions in icosahedral molecules. This work is the first comprehensive theoretical analysis of the Jahn-Teller interaction in C60 and other icosahedral compl...
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Chancey, C. C., author. aut http://id.loc.gov/vocabulary/relators/aut The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / C. C. Chancey, M. C.M. O'Brien. Princeton, NJ : Princeton University Press, [2022] ©1998 1 online resource (221 p.) : 30 tables 45 line illus. text txt rdacontent computer c rdamedia online resource cr rdacarrier text file PDF rda Frontmatter -- Contents -- LIST OF FIGURES -- LIST OF TABLES -- GLOSSARY OF SYMBOLS -- The Jahn-Teller Effect in C60 and Other Icosahedral Complexes -- 1. Introduction -- 2. Icosahedral Symmetry and Its Effects -- 3. T⦻h and p"⦻h -- 4. Electronic Quartets and G⦻(g ⊕ h) -- 5. Electronic Quintets and H⦻(g ⊕ h) -- 6. Bridge to Experiment -- Appendixes -- A. Adiabatic Approximation -- B. Quantum Tunneling Energies -- C. E⦻€ -- D. The Group l -- E. Jahn-Teller Interaction Matrices and Their Bases -- F. Transformations -- G. Parameters of the Jahn-Teller Minima and Other Stationary Points -- H. Cited References and Bibliography -- INDEX restricted access http://purl.org/coar/access_right/c_16ec online access with authorization star Because of the high symmetry involved, the Jahn-Teller effect is the natural starting point for considering electron-phonon (or vibronic) interactions in icosahedral molecules. This work is the first comprehensive theoretical analysis of the Jahn-Teller interaction in C60 and other icosahedral complexes. The importance of this research derives in part from the increasing, widespread interest in C60 and other molecular clusters and their application in science and industry. The electrical and spectroscopic properties of fullerene and fulleride compounds depend intimately on the coupling between the electronic and vibrational modes of these systems, and this book addresses the fundamental theoretical questions. In particular, a chapter is devoted to the connection between the theory and experimental observations, such as ESR (electron spin resonance) effects and molecular spectra. Earlier books have discussed the theory of Jahn-Teller interactions in lower symmetry structures (cubic, tetrahedral, tetragonal, trigonal,.); this is the first that focuses on the new icosahedral systems, whose most famous example is Buckminsterfullerene, C60. The book's authors have over fifty years of combined research experience into the theoretical aspects of the Jahn-Teller effect. Mode of access: Internet via World Wide Web. In English. Description based on online resource; title from PDF title page (publisher's Web site, viewed 29. Jun 2022) Buckminsterfullerene Spectra. Chemistry. Electronic structure. Fullerenes Spectra. Icosahedra. Jahn-Teller effect. SCIENCE / Physics / General. bisacsh APES vertical matrix elements. Basis states for irreps of I. Biharmonic Variables. Born-Oppenheimer approximation. Born-Oppenheimer products. Cluster Hamiltonian. Cluster model Ham factors. Cluster models. Crystal fields lowering symmetry. Dynamic JT effect. Electron spin resonance (esr). Electron-phonon interactions. Epikernel Principle. Franck-Condon principle. Ground states, cluster model. Group I, spin representations. Hyperspherical coordinates. I double group. Icosahedral clusters. Icosahedron, vertices. Interaction matrices. JT active modes. JT effect dynamic. Jahn-Teller theorem. Kramers degeneracy. Lanczos process, modified. Line spectra, multimode. Multi-mode Hamiltonian. Multi-mode effects. Numerical phase tracking. Optical absorption, band spectra. Parameters of minima. Quadratic Jahn-Teller effect. Quantum tunneling energies. Random strains. Rotating distortions. Rotational symmetry. Second quantization. Sloncjewski resonances. Spectra, experimental. Spectra, selection rules. Spin Hamiltonian. Strain lowering symmetry. Symmetry lowering strains. Time reversal degeneracy. Tunneling integral. Tunneling. Vertical transitions. WKB approximation. WKB in one dimension. O'Brien, M. C.M., author. aut http://id.loc.gov/vocabulary/relators/aut Title is part of eBook package: De Gruyter Princeton University Press eBook-Package Archive 1927-1999 9783110442496 Title is part of eBook package: De Gruyter Princeton University Press eBook-Package Gap Years 9783110784237 https://doi.org/10.1515/9780691225340?locatt=mode:legacy https://www.degruyter.com/isbn/9780691225340 Cover https://www.degruyter.com/document/cover/isbn/9780691225340/original |
language |
English |
format |
eBook |
author |
Chancey, C. C., Chancey, C. C., O'Brien, M. C.M., |
spellingShingle |
Chancey, C. C., Chancey, C. C., O'Brien, M. C.M., The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / Frontmatter -- Contents -- LIST OF FIGURES -- LIST OF TABLES -- GLOSSARY OF SYMBOLS -- The Jahn-Teller Effect in C60 and Other Icosahedral Complexes -- 1. Introduction -- 2. Icosahedral Symmetry and Its Effects -- 3. T⦻h and p"⦻h -- 4. Electronic Quartets and G⦻(g ⊕ h) -- 5. Electronic Quintets and H⦻(g ⊕ h) -- 6. Bridge to Experiment -- Appendixes -- A. Adiabatic Approximation -- B. Quantum Tunneling Energies -- C. E⦻€ -- D. The Group l -- E. Jahn-Teller Interaction Matrices and Their Bases -- F. Transformations -- G. Parameters of the Jahn-Teller Minima and Other Stationary Points -- H. Cited References and Bibliography -- INDEX |
author_facet |
Chancey, C. C., Chancey, C. C., O'Brien, M. C.M., O'Brien, M. C.M., O'Brien, M. C.M., |
author_variant |
c c c cc ccc c c c cc ccc m c o mc mco |
author_role |
VerfasserIn VerfasserIn VerfasserIn |
author2 |
O'Brien, M. C.M., O'Brien, M. C.M., |
author2_variant |
m c o mc mco |
author2_role |
VerfasserIn VerfasserIn |
author_sort |
Chancey, C. C., |
title |
The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / |
title_full |
The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / C. C. Chancey, M. C.M. O'Brien. |
title_fullStr |
The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / C. C. Chancey, M. C.M. O'Brien. |
title_full_unstemmed |
The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / C. C. Chancey, M. C.M. O'Brien. |
title_auth |
The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / |
title_alt |
Frontmatter -- Contents -- LIST OF FIGURES -- LIST OF TABLES -- GLOSSARY OF SYMBOLS -- The Jahn-Teller Effect in C60 and Other Icosahedral Complexes -- 1. Introduction -- 2. Icosahedral Symmetry and Its Effects -- 3. T⦻h and p"⦻h -- 4. Electronic Quartets and G⦻(g ⊕ h) -- 5. Electronic Quintets and H⦻(g ⊕ h) -- 6. Bridge to Experiment -- Appendixes -- A. Adiabatic Approximation -- B. Quantum Tunneling Energies -- C. E⦻€ -- D. The Group l -- E. Jahn-Teller Interaction Matrices and Their Bases -- F. Transformations -- G. Parameters of the Jahn-Teller Minima and Other Stationary Points -- H. Cited References and Bibliography -- INDEX |
title_new |
The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / |
title_sort |
the jahn-teller effect in c60 and other icosahedral complexes / |
publisher |
Princeton University Press, |
publishDate |
2022 |
physical |
1 online resource (221 p.) : 30 tables 45 line illus. |
contents |
Frontmatter -- Contents -- LIST OF FIGURES -- LIST OF TABLES -- GLOSSARY OF SYMBOLS -- The Jahn-Teller Effect in C60 and Other Icosahedral Complexes -- 1. Introduction -- 2. Icosahedral Symmetry and Its Effects -- 3. T⦻h and p"⦻h -- 4. Electronic Quartets and G⦻(g ⊕ h) -- 5. Electronic Quintets and H⦻(g ⊕ h) -- 6. Bridge to Experiment -- Appendixes -- A. Adiabatic Approximation -- B. Quantum Tunneling Energies -- C. E⦻€ -- D. The Group l -- E. Jahn-Teller Interaction Matrices and Their Bases -- F. Transformations -- G. Parameters of the Jahn-Teller Minima and Other Stationary Points -- H. Cited References and Bibliography -- INDEX |
isbn |
9780691225340 9783110442496 9783110784237 |
callnumber-first |
Q - Science |
callnumber-subject |
QC - Physics |
callnumber-label |
QC176 |
callnumber-sort |
QC 3176.8 E4 |
url |
https://doi.org/10.1515/9780691225340?locatt=mode:legacy https://www.degruyter.com/isbn/9780691225340 https://www.degruyter.com/document/cover/isbn/9780691225340/original |
illustrated |
Illustrated |
dewey-hundreds |
500 - Science |
dewey-tens |
540 - Chemistry |
dewey-ones |
546 - Inorganic chemistry |
dewey-full |
546/.681 |
dewey-sort |
3546 3681 |
dewey-raw |
546/.681 |
dewey-search |
546/.681 |
doi_str_mv |
10.1515/9780691225340?locatt=mode:legacy |
oclc_num |
1312725988 |
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The Jahn-Teller Effect in C60 and Other Icosahedral Complexes / |
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